What you have to do from there is to wire the t-stat to the boiler so it picks up the line (Hot wire) from the circulator. This will "Only" allow the boiler to fire if there is power to the circulator. You DON"T want a situation where the boiler can fire without the circulator running. You currently have this possiblity. If you put the boiler t-stat sensor on the return bay loop pipe, Then the boiler will cycle on/off based on return glycol temp. The boiler t-stat has to have differential capability. Not all t-stats are the same. I have mine set with 10° differential. The boiler kicks on at 60° and off @ 70°. This gives me an average of 15 minutes on - 15 minute off to complete the cycle. Even though you are picking up heat through the PVC pipe, it will be consistant. So you may have toplay with the diffential and setpoint of the boiler t-stat to get it dialed in. But once you have it set, it will repeat.
When the outside temp goes above 32°, it cuts power to the circulator which in turn cuts power to the boiler t-stat thus shutting the whole system down...