Good catch! Wonder how many years I have left?! My system just turned 12yo....The gpm through my heater has remained unchanged at 6.0gpm the entire time, even with the tiny passages in the Takagi Heat Exchanger....I think that reading would be a good value to monitor to see if/when an issue with corrosion is affecting how well the system works. If I remember correctly, the cost of brass or SS flanges and pump housings scared the hell out of me! My pockets wern't very deep then! I can only imagine the price now! I'm hoping the paint Taco uses is an isolator!!! Jk....It looks like you have cast iron pump flanges with a brass nipple between the two pumps.
There is also a very fine mesh and tiny screen filter in the inlet to the heater. I posted I had issues in the beginning with this filter plugging because I ran a "cleaner" in the system before filling with propylene glycol....I ran a 5 micron filter in line for a day or two to filter the system. Since then, I have never had to take the small filter out to clean it....
Here is a short but good read that CantBreak80 just sent me...Explains a lot and some preventative measures you can take like maintaining propper PH to extend the systme life, even in a system with dissimilar metals.
How water behaves in hydronic systems - HPAC MagazineHPAC Magazine