That looks similar to some we used to use. The secondary is a two taps. Purple is 24 common, Red is 24 hot if you have 230 on the primary and the red/white is 24 if you have 208 primary on ours.
I'm not familiar with the primary wire colors. Is there any markings on it?
Is the one with the 220 single phase the same transformer? Looks pretty large. Can you find a VA rating?